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Ce3+ -ion, Surface Oxygen Vacancy, and Visible Light-induced Photocatalytic Dye Degradation and Photocapacitive Performance of CeO2-Graphene Nanostructures

Cerium oxide nanoparticles (CeO2 NPs) were fabricated and grown on graphene sheets using a facile, low cost hydrothermal approach and subsequently characterized using different standard characterization techniques. X-ray photoelectron spectroscopy and electron paramagnetic resonance revealed the changes in surface states, composition, changes in Ce4+ to Ce3+ ratio, and other defects. Transmission electron microscopy (TEM) and high resolution TEM revealed that the fabricated CeO2 NPs to be…See More
Jul 28

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Dr.Engr.D.Nirmal Tej Kumar liked Mohammad Mansoob Khan's blog post Ce3+ -ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nanocomposite
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MOHAMMAD EHTISHAM KHAN commented on Mohammad Mansoob Khan's blog post Ce3+ -ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nanocomposite
"Congratulation!!!!  Great contribution in the field of Nanoscience and Nanotechnology."
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MOHAMMAD EHTISHAM KHAN liked Mohammad Mansoob Khan's blog post Ce3+ -ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nanocomposite
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MOHAMMAD EHTISHAM KHAN commented on Mohammad Mansoob Khan's blog post CdS-graphene Nanocomposite for Efficient Visible-light-driven Photocatalytic and Photoelectrochemical Applications
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Profile Information

I am...
Chemist, Teacher
My research field or area of interest innanotechnology
Nanoparticles and nanocomposites synthesis

Microbial Fuel Cells

Electrochemically Active Biofils

Graphene
Interest in...
Nanosciences

Band gap engineering

Metal nanoparticles,

metal-metal oxide nanocomposites,

band gap engineering,

graphene,


metal-graphene nanocomposites,

Photocatalysis,

Sensor

Bio-hydrogen production
Publication list
60. R. Saravanan, M. Mansoob Khan, F. Gracia, J. Qin, V. K. Gupta, and A. Stephen, Ce3+ -ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nanocomposite. Scientific Reports 2016, 6, 31641.

59. M. E. Khan, M. Mansoob Khan, and M. H. Cho, CdS-graphene Nanocomposite for Efficient Visible-light-driven Photocatalytic and Photoelectrochemical Applications. Journal of Colloid and Interface Science, 2016, 482, 221-232.

59. R. Saravanana, E. Sacari, F. Gracia, M. Mansoob Khan, E. Mosquera, V. K. Gupta, Conducting PANI stimulated ZnO system for visible light photocatalytic degradation of coloured dyes. Journal of Molecular Liquids 2016, 221, 1029–1033.

58. Y. I. Choi, S. Lee, S. K. Kim, Y. I. Kim, D. W. Cho, M. Mansoob Khan, Y. Sohn, Fabrication of ZnO, ZnS, Ag-ZnS, and Au-ZnS microspheres for photocatalytic activities, CO oxidation and 2-hydroxyterephthalic acid synthesis. Journal of Alloys and Compounds 2016, 675, 46 - 56.

57. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, and M. H. Cho, Nitrogen-doped titanium dioxide (N-doped TiO2) for visible light photocatalysis. New Journal of Chemistry, 2016, 3000--3009.

56. M. E. Khan, M. Mansoob Khan, and M. H. Cho, Fabrication of WO3 nanorods on graphene nanosheets for improved visible light-induced photocapacitive and photocatalytic performance. RSC Advances, 2016, 6, 20824-20833.

55. Young In Choi, Kyung Hee Jeon, Hye Sun Kim, Jun Hyok Lee, Seong Jun Park, Jang Eon Roh, Mohammad Mansoob Khan, Youngku Sohn, TiO2/BiOX (X = Cl, Br, I) hybrid microspheres for artificial waste water and real sample treatment under visible light irradiation. Separation and Purification Technology, 2016,60,28–42.

54. M. Mansoob Khan, Editorial for Special Issue “Nanomaterials as Photocatalysts” Journal of Saudi Chemical Society 2015, 19, 461.

53. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, and M. H. Cho, Electrically conductive polyaniline sensitized defective-TiO2 for improved visible light photocatalytic and photoelectrochemical performance: A synergistic effect. New Journal of Chemistry 2015, DOI: 10.1039/C5NJ01127B. [SCI, I.F. 3.1].

52. M. E. Khan, M. Mansoob Khan, and M. H. Cho, Biogenic synthesis of a Ag–graphene nanocomposite with efficient photocatalytic degradation, electrical conductivity and photoelectrochemical performance. New Journal of Chemistry 2015, 39, 8121-8129. [SCI, I.F. 3.1].

51. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, and M. H. Cho, Polythiophene nanocomposites for photodegradation applications: Past, present and future. Journal of Saudi Chemical Society, 2015, 19, 494–504. [SCI, I.F. 2.5].

50. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, and M. H. Cho, Polythiophene nanocomposites for photodegradation applications: Past, present and future. Journal of Saudi Chemical Society, 2015, DOI:10.1016/j.jscs.2015.06.004. [SCI, I.F. 2.5].

49. R. Saravanan, F. Gracia, M. Mansoob Khan, V. Poornima, V. K. Gupta, V. Narayanan and A. Stephen, ZnO/CdO nanocomposites for textile effluent degradation and electrochemical detection. J. of Molecular Liquids 2015, 209, 374–380. [SCI, I.F. 2.5].

48. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, and M. H. Cho, Silver nanoparticles and defect-induced visible light photocatalytic and photoelectrochemical performance of Ag@m-TiO2 nanocomposite. Solar Energy Materials & Solar Cells, 2015, 141, 162–170. [SCI, I.F. 5.3].

47. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, and M. H. Cho, DC Electrical Conductivity Retention and Electrical Compensation of Polyaniline by TiO2 at Higher Loading Percentages in Polyaniline@TiO2 Nanocomposites. Electron. Mater. Lett., 2015, DOI: 10.1007/s13391-015-5073-2. [SCI, I.F. 2.6].

46. M. Mansoob Khan, S. F. Adil, and A. A. Mayouf, Metal oxides as Photocatalysts. Journal of Saudi Chemical Society, 2015, DOI:10.1016/j.jscs.2015.04.003. [SCI, I.F. 2.5].

45. R. Saravanan, M. Mansoob Khan, V. K. Gupta, E. Mosquera, F. Gracia, V. Narayanan and A. Stephen, ZnO/Ag/CdO nanocomposite for visible light-induced photocatalytic degradation of industrial textile effluents. Journal of Colloid and Interface Science, 2015, 452, 126–133. [SCI, I.F. 3.6].

44. R. Saravanan, M. Mansoob Khan, V. K. Gupta, E. Mosquera, F. Gracia, V. Narayanan and A. Stephen, ZnO/Ag/Mn2O3 nanocomposite for visible lightinduced industrial textile effluent degradation, uric acid and ascorbic acid sensing and antimicrobial activity. RSC Adv., 2015, 5, 34645–34651. [SCI, I.F. 3.71].

43. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, and M. H. Cho, Improved electrode performance in microbial fuel cells and the enhanced visible light-induced photo-electrochemical behavior of PtOx@M-TiO2 nanocomposites. Ceramics International 2015, 41 9131–9139. [SCI, I.F. 2.60].

42. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, and M. H. Cho, Gold nanoparticle-sensitized wide and narrow band gap TiO2 for visible light applications: a comparative study. New Journal of Chemistry, 2015, 39, 4708-4715. [SCI, I.F. 3.16].

41. M. E. Khan, M. Mansoob Khan, and M. H. Cho, Green synthesis, photocatalytic and photoelectrochemical performance of an Au–Graphene nanocomposite. RSC Advances, 2015, 5, 26897–26904. [SCI, I.F. 3.71].

40. M. Mansoob Khan, S. A. Ansari, M. E. Khan, M. O. Ansari, and M. H. Cho, Visible light-induced enhanced photoelectrochemical and photocatalytic studies of gold decorated SnO2 nanostructures. New Journal of Chemistry, 2015, 39, 2758–2766. [SCI, I.F. 3.16].

39. M. Mansoob Khan, S. A. Ansari, J. H. Lee, M. O. Ansari, J. Lee and M. H. Cho, Electrochemically active biofilm assisted synthesis of Ag@CeO2 nanocomposites for antimicrobial activity, photocatalysis and photoelectrodes. Journal of Colloid and Interface Science, 2014, 431, 255–263. [SCI, I.F. 3.2].

38. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, J. Lee and M. H. Cho, Visible light-driven photocatalytic and photoelectrochemical studies of Ag-SnO2 nanocomposites synthesized using an electrochemically active biofilm. RSC Advances, 2014, 4, 26013–26021. [SCI, I.F. 3.71].

37. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, J. Lee and M. H. Cho, Enhanced Thermal Stability under DC Electrical Conductivity Retention and Visible Light Activity of Ag/TiO2@Polyaniline Nanocomposite Film. ACS Applied Materials & Interfaces, 2014, 6, 8124–8133. [SCI, I.F. 5.90].

36. M. Mansoob Khan, S. A. Ansari, D. Pradhan, D. H. Han, J. Lee and M. H. Cho, Defect-Induced Band Gap Narrowed CeO2 Nanostructures for Visible Light Activities. Industrial & Engineering Chemistry Research, 2014, 53, 9754–9763. [SCI, I.F. 2.3].

35. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, J. Lee and M. H. Cho, Enhanced thermoelectric behaviour and visible light activity of Ag@TiO2/Polyaniline nanocomposite synthesized by biogenic-chemical route. RSC Advances, 2014, 4, 23713-23719. [SCI, I.F. 3.71].

34. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, J. Lee and M. H. Cho, Highly photoactive SnO2 nanostructures engineered by electrochemically active biofilm. New Journal of Chemistry 2014, 38, 2462−2469. [SCI, I.F. 3.16]

33. M. Mansoob Khan, S. A. Ansari, M. O. Ansari, B. D. Min, J. Lee, M. H. Cho, Biogenic fabrication of Au@CeO2 nanocomposite with enhanced visible light activity. Journal of Physical Chemistry C, 2014, 118, 9477−9484. [SCI, I.F. 4.84]

32. T. H. Han, M. Mansoob Khan, J. Lee and M. H. Cho, Optimization of gold nanoparticles synthesis by stainless steel for H2O2 and glucose detection. Journal of Industrial and Chemical Engineering, 2014, 20, 2003–2009. [SCI, I.F. 2.10]

31. M. Mansoob Khan, J. Lee and M. H. Cho, Au@TiO2 nanocomposites with high catalytic activity for degradation of methyl orange and methylene blue–An electron relay effect. Journal of Industrial and Chemical Engineering, 2014, 20, 1584–1590 [SCI, I.F. 2.10]

30. S. A. Ansari, M. Mansoob Khan, J. Lee and M. H. Cho, Highly visible light active Ag@ZnO nanocomposites synthesized by gel-combustion route. Journal of Industrial and Chemical Engineering, 2014, 20, 1602–1607. [SCI, I.F. 2.10]

29. M. Mansoob Khan, Spectroscopic and Physico-chemical Characterization of Ir(I) and Ru(III) Complexes of 32-Membered Unsymmetrical Dinucleating Macrocyclic Ligand. J. of Inclusion Phenomena and Macrocyclic Chemistry, 2014, 78, 257–263. [SCI, I.F. 1.43]

28. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, J. Lee and M. H. Cho, Band Gap Engineering of CeO2 Nanostructure by Electrochemically Active Biofilm for Visible Light Applications. RSC Advances 2014, 4, 16782-16791, [SCI, I.F. 3.71].

27. M. Mansoob Khan, S. A. Ansari, J. H. Lee, J. Lee and M. H. Cho, Mixed Culture Electrochemically Active Biofilms and their Microscopic and Spectroelectrochemical Studiess. ACS Sustainable Chem. Eng. 2014, 2, 423−432, [SCI, I.F. 5.0 expected].

26. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, I. Amal, J. Lee and M. H. Cho, pTSA doped conducting graphene/polyaniline nanocomposite fibers: Thermoelectric behavior and electrode analysis, Chemical Engineering Journal, 2014, 242, 155–161. [SCI, I.F. 4.1].

25. M. Mansoob Khan, S. A. Ansari, D. Pradhan, M. O. Ansari, D. H. Han, J. Lee and M. H. Cho, Band gap engineered TiO2 nanoparticles for visible light induced photoelectrochemical and photocatalytic studies. Journal of Materials Chemistry A, 2014, 2, 637–644. [SCI, I.F. ~6.0]

24. M. O. Ansari, M. Mansoob Khan, S. A. Ansari, I. Amal, J. Lee and M. H. Cho, Enhanced thermoelectric performance and ammonia sensing properties of sulfonated polyaniline/graphene thin films, Materials Letters, 2014, 114, 159–162. [SCI, I.F. 2.3]

23. S. A. Ansari, M. Mansoob Khan, M. O. Ansari, J. Lee and M. H. Cho, Biogenic Synthesis, Photocatalytic and Photoelectrochemical Performance of Ag-ZnO Nanocomposite. The Journal of Physical Chemistry C, 2013, 117, 27023–27030. [SCI, I.F. 4.84]

22. M. Mansoob Khan, S. A. Ansari, J. Lee and M. H. Cho, Novel Ag@TiO2 nanocomposite synthesized by electrochemically active biofilm for nonenzymatic hydrogen peroxide sensor. Materials Science & Engineering C, 2013, 33, 4692–4699. [SCI, I.F. 2.74]

21. S. A. Ansari, M. Mansoob Khan, S. Kalathil, A. Nisar, J. Lee and M. H. Cho, Oxygen Vacancy Induced Band Gap Narrowing of ZnO Nanostructure by Electrochemically Active Biofilm. Nanoscale, 2013, 5, 9238–9246. [SCI, I.F. 6.73]

20. S. Kalathil, N. V. Hoa, J. J. Shim, M. Mansoob Khan, J. Lee and M. H. Cho, Enhanced Performance of a Microbial Fuel Cell Using CNT/MnO2 Nanocomposites as a Bioanode Materials. J. of Nanoscience and Nanotechnology, 2013, 13, 7712–7716. [SCI, I.F. 1.6]

19. M. Mansoob Khan, S. A. Ansari, J. Lee and M. H. Cho, Enhanced optical, visible light catalytic and electrochemical properties of Au@TiO2 nanocomposites. Journal of Industrial and Engineering Chemistry, 2013, 19, 1845–1850. [SCI, I.F. 2.10]

18. S. Kalathil, M. Mansoob Khan, J. Lee and M. H. Cho, Production of bioelectricity, bio-hydrogen, high value chemicals and bioinspired nanomaterials by electrochemically active biofilms. Biotechnology Advances, 2013, 31, 915–924. [SCI, I.F. 8.5]

17. T. H. Han, M. Mansoob Khan, S. Kalathil, J. Lee and M. H. Cho, Simultaneous enhancement of the methylene blue degradation and power generation in microbial fuel cell by gold nanoparticles. ACS Industrial & Engineering Chemistry Research, 2013, 3, 52, 8174–8181. [SCI, I.F. 2.2]

16. M. Mansoob Khan, S. Kalathil, T. H. Han, J. Lee and M. H. Cho, Positively Charged Gold Nanoparticles Synthesized by Electrochemically Active Biofilm – A Biogenic Approach. J. of Nanoscience and Nanotechnology, 2013, 13, 6079–6085. [SCI, I.F. 1.6]

15. S. Kalathil, M. Mansoob Khan, S. A. Ansari, J. Lee and M. H. Cho, Band gap narrowing of titanium dioxide (TiO2) nanocrystals by electrochemically active biofilm and their visible light activity. Nanoscale, 2013, 5, 6323–6326. [SCI, I.F. 6.73]

14. M. Mansoob Khan, S. A. Ansari, J. Lee and M. H. Cho, Highly Visible Light Active Ag@TiO2 Nanocomposites Synthesized by Electrochemically Active Biofilm: A Novel Biogenic Approach. Nanoscale, 2013, 5, 4427–4435. [SCI, I.F. 6.73]

13. T. H. Han, M. Mansoob Khan, S. Kalathil, J. Lee and M. H. Cho, Synthesis of positively charged gold nanoparticles using a stainless steel mesh. Journal of Nanoscience and Nanotechnology, 2013, 13, 6140–6144. [SCI, I.F. 1.6]

12. M. Mansoob Khan, J. Lee and M. H. Cho, Electrochemically Active Biofilm Mediated Bio-hydrogen Production Catalyzed by Positively Charged Gold Nanoparticles. International Journal of Hydrogen Energy, 2013, 38, 5243–5250. [SCI, I.F. 2.93]

11. S. Kalathil, M. Mansoob Khan, J. Lee and M. H. Cho, A Simple Biogenic-Route to Au@TiO2 Nanocomposites Synthesis Using Electrochemically Active Biofilms by TiO2 Assistance and their Enhanced Photocatalytic Activities. Journal of Nanoparticle Research, 2012, 14, 1051–1060. [SCI, I.F. 2.18]

10. M. Mansoob Khan, S. Kalathil, J. Lee and M. H. Cho, Synthesis of Cysteine Capped Silver Nanoparticles by Electrochemically Active Biofilm and their Antibacterial Activities. Bulletin of Korean Chemical Society, 2012, 33, 8, 2592–2596. [SCI, I.F. 0.98]

9. M. Mansoob Khan, S. Kalathil, J. Lee and M. H. Cho, Enhancement in the Photocatalytic Activity of Au@TiO2 Nanocomposites by Pretreatment of TiO2 with UV light. Bulletin of Korean Chemical Society, 2012, 33, 5, 1753–1758. [SCI, I.F. 0.98]

8. M. Mansoob Khan, Novel Applications of Nanowires in Different Aspects of Life. A Short Review, Journal of Industrial Research and Technology, 2011, 1, 2, 135–146.

7. M. Mansoob Khan, Ru(III), Pd(II), Pt(III) and Pt(IV) Complexes of a Novel 32-Membered Unsymmetrical Macrocyclic Ligand. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2010, 40, 3, 148–152. [SCI, I.F. 0.7]

6. M. Mansoob Khan, M. Admassu and H. R. Sharma, Suitability assessment of water quality of Shinta River and its impacts on the users: A case study from Gondar, Ethiopia. Indian Journal of Environmental Protection, 2009, 29, 2, 137–144.

5. Z. A. Siddiqi, M. Mansoob Khan, M. Khalid and S. Kumar, Spectral and electrochemical characterization of bimetallic complexes of a novel 32-membered unsymmetrical [N12] macrocycle. Transition Metal Chemistry, 2007, 32, 927–935. [SCI, I.F. 1.4]

4. Lutfullah, A. Umar, M. M. Rahman, M. Mansoob Khan and Y. B. Hahn, Synthesis, Physico-chemical and Spectroscopic Investigations of Sodium Dihydrobis(1,2,3-benzotriazolyl)borate Ligand and its Transition Metal Complexes. Turkish J. Chemistry, 2007, 31, 179–189. [SCI, I.F. 0.6]

3. Z. A. Siddiqi, M. Mansoob Khan and M. Khalid, Synthesis and Spectral Studies of a Novel 20-membered Unsymmetrical Dinucleating [N8] Macrocycle and its Bimetallic Complexes, M2LCln(ClO4)2 (n = 2, M = Co, Ni or Cu; N = 4, M = Cr or Fe). Polish J. Chemistry, 2006, 80, 377–386. [SCI, I.F. 0.5]

2. Z. A. Siddiqi and M. Mansoob Khan, Synthesis and Characterization of a Novel 32-membered Unsymmetrical Dinucleating [N12] Macrocycle: preparation of bimetallic Complexes M2LX2(ClO4)2 (M = Zn, Cd or Hg; X = Cl, NCS or NO3). Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2004, 34, 5, 897–917. [SCI, I.F. 0.7]

1. Z. A. Siddiqi, V. J. Mathew and M. Mansoob Khan, Synthesis and Physico-Chemical Investigations on 16 and 18 membered [N4] macrocycles Modified with appropriate Carbonyl Functions _A closer mimic to a synthetic cyclic tetrapeptide; isolations of stable encapsulated derivatives with Zn(II), Cd(II) and Hg(II) ions. Main Group Metal Chemistry, 2002, 24, 12, 857–864. [SCI, I.F. 0.6]
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Mohammad Mansoob Khan's Blog

Ce3+ -ion, Surface Oxygen Vacancy, and Visible Light-induced Photocatalytic Dye Degradation and Photocapacitive Performance of CeO2-Graphene Nanostructures

Posted on July 28, 2017 at 12:24pm 0 Comments

Cerium oxide nanoparticles (CeO2 NPs) were fabricated and grown on graphene sheets using a facile, low cost hydrothermal approach and subsequently characterized using different standard characterization techniques. X-ray photoelectron spectroscopy and electron paramagnetic resonance revealed the changes in surface states, composition, changes in Ce4+ to Ce3+ ratio, and other defects. Transmission electron…

Continue

CdS-graphene Nanocomposite for Efficient Visible-light-driven Photocatalytic and Photoelectrochemical Applications

Posted on October 8, 2016 at 10:31am 1 Comment

This paper reports cadmium sulphide nanoparticles-(CdS NPs)-graphene nanocomposite (CdS-Graphene), prepared by a simple method, in which CdS NPs were anchored/decorated successfully onto graphene sheets. The as-synthesized nanocomposite was characterized using standard characterization techniques. A combination of CdS NPs with the optimal amount of two-dimensional graphene sheets had a profound influence on the properties of the resulting hybrid nanocomposite, such as enhanced optical,…

Continue

Ce3+ -ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nanocomposite

Posted on October 8, 2016 at 10:30am 1 Comment

In this study, pure ZnO, CeO2 and ZnO/CeO2 nanocomposites were synthesized using a thermal decomposition method and subsequently characterizhttp://www.nature.com/articles/srep31641ed using different standard techniques. High-resolution X-ray photoelectron spectroscopy measurements confirmed the oxidation states and presence of Zn2+,…

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CdS-graphene Nanocomposite for Efficient Visible-light-driven Photocatalytic and Photoelectrochemical Applications

Posted on October 8, 2016 at 10:27am 0 Comments

This paper reports cadmium sulphide nanoparticles-(CdS NPs)-graphene nanocomposite (CdS-Graphene), prepared by a simple method, in which CdS NPs were anchored/decorated successfully onto graphene sheets. The as-synthesized nanocomposite was characterized using standard characterization techniques. A combination of CdS NPs with the optimal amount of two-dimensional graphene sheets had a profound influence on the properties of the resulting hybrid nanocomposite, such as enhanced optical,…

Continue

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At 3:08pm on October 9, 2016,
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KHADEEJA YASMEEN
said…
Congrats sir
 
 
 

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